https://doi.org/10.1140/epjd/e2009-00030-0
Stoichiometry analysis of titanium oxide coating by LIBS
1
Grupo de Investigaciones en Corrosión, Universidad Industrial de Santander, A.A., 678 Bucaramanga, Colombia
2
Laboratorio de Espectroscopia Atómica y Molecular, Universidad Industrial de Santander, A.A., 678 Bucaramanga, Colombia
Corresponding author: a emejia@uis.edu.co
Received:
25
July
2008
Revised:
18
December
2008
Published online:
13
February
2009
In this work, laser induced breakdown spectroscopy (LIBS) is used to determine the composition of titanium oxide film produced by anodized of Ti6Al4V alloy. We have used Ti lines in the spectral region between 470–520 nm to determine temperature of the plasma generated on anodized surface of Ti6Al4V alloy for temperature determination by Boltzmann plot method. In order to measure the content of oxygen and titanium ratio on the surface the alloy, we have used the oxygen lines 777.194, 777.417 and 777.539 nm, and titanium lines 780.597 and 782.491 nm observed in an ambient of argon. Finally, we report the possibilities for the determination of the coating chemical composition using LIBS.
PACS: 79.20.Ds – Laser-beam impact phenomena / 78.66.Bz – Metals and metallic alloys / 52.25.Os – Emission, absorption, and scattering of electromagnetic radiation / 52.38.Mf – Laser ablation
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2009