Doublet and quartet states of Li-2
Centre de Physique Théorique, CNRS, Luminy Case 907, 13288 Marseille Cedex 9, France
Corresponding author: a firstname.lastname@example.org
Published online: 15 January 2000
Electronic states of the molecular lithium anion are investigated by configuration-interaction calculations. Comparison with the analogously computed potential energy curves for the lowest singlet and triplet states of the neutral Li2 shows that in addition to the well-known stable ground state X there also exist metastable excited states of Li. Within the quartet sector, two candidates for such long-lived states are identified and their spectroscopic properties studied.
PACS: 31.15.Ar – Ab initio calculations / 33.15.Fm – Bond strengths, dissociation energies / 33.15.Dj – Interatomic distances and angles
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2000