https://doi.org/10.1140/epjd/e2016-70180-y
Regular Article
Negative ion resonances in carbon monoxide*
Probing dissociative electron attachment in CO by velocity slice imaging
1 Tata Institute of Fundamental
Research, Homi Bhabha Road,
Colaba, 400005
Mumbai,
India
2 Department of Physics and Astronomy,
The Open University, Walton
Hall, Milton
Keynes, MK7 6AA,
UK
a
e-mail: ekkumar@tifr.res.in
Received:
9
March
2016
Received in final form:
4
May
2016
Published online:
14
June
2016
Dissociative electron attachment to CO leading to the formation of O− is studied using the velocity slice imaging technique. The angular distributions we obtained for the C(3P) and the C(1D) limits are found to be considerably different from a recent set of measurements [Tian et al., Phys. Rev. A 88, 012708 (2013); Wang et al., J. Chem. Phys. 143, 066101 (2015)] using a similar technique. The analysis of our results indicate incoherent contributions from states of Σ and Π symmetries to both these dissociation channels and rules out the need to invoke coherent excitation of several resonances, in contrast to what has been done in the above publications. We try to correlate these resonances to those observed in inelastic scattering and transmission experiments. We also confirm the presence of a third dissociation channel leading to C(1S) limit.
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag 2016