https://doi.org/10.1140/epjd/e2014-40570-4
Regular Article
Effects of rotation in the energy spectrum of C60
1 Departamento de Física, CCEN,
Universidade Federal da Paraíba, Caixa Postal 5008, 58051-900
João Pessoa, PB, Brazil
2 Departamento de Física, CCEN,
Universidade Federal de Pernambuco, 50670-901
Recife, PE, Brazil
a
e-mail: jonas.iasd@gmail.com
Received:
12
September
2013
Received in final form:
4
February
2014
Published online:
24
April
2014
In this paper, motivated by the experimental evidence of rapidly rotating C60 molecules in fullerite, we study the low-energy electronic states of rotating fullerene within a continuum model. In this model, the low-energy spectrum is obtained from an effective Dirac equation including non-Abelian gauge fields that simulate the pentagonal rings of the molecule. Rotation is incorporated into the model by solving the effective Dirac equation in the rotating referential frame. The exact analytical solution for the eigenfunctions and energy spectrum is obtained, yielding the previously known static results in the no rotation limit. Due to the coupling between rotation and total angular momentum, that appears naturally in the rotating frame, the zero modes of static C60 are shifted and also suffer a Zeeman splitting whithout the presence of a magnetic field.
Key words: Molecular Physics and Chemical Physics
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag 2014