Eur. Phys. J. D (2012) 66: 204
https://doi.org/10.1140/epjd/e2012-30200-8

Regular Article

R-matrix calculations of differential and integral cross sections for low-energy electron collisions with ethanol

Department of Physics and Astronomy, University College London, Gower St., WC1E 6 BT London, UK

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Received: 26 March 2012
Received in final form: 29 April 2012
Published online: 16 August 2012

Abstract

Electron collisions with C₂H₅OH are studied up to impact energies of 10 eV using several theoretical models. Calculated differential cross sections suggest that the extrapolation to low angles used to extend experimental data and hence give integral cross sections significantly underestimates the large, dipole-driven forward scattering cross section. An improved set of values for the rotationally-unresolved elastic cross section is proposed; the corresponding rotationally resolved cross sections are also presented. Static exchange plus polarisation calculations find a very broad shape resonance in each of the ²A′ and ²A′′ symmetries in the 7 eV collision region however no resonance at lower energies, in qualitative agreement with the interpretation of some but not all dissociative electron attachment measurements.