https://doi.org/10.1140/epjd/e2010-10413-7
Ab initio dipole polarizabilities and quadrupole moments of the lowest excited states of atomic Yb
Department of Chemistry, Moscow State University, Moscow, 119991, Russia
Corresponding author: a alexei@classic.chem.msu.su
Received:
20
July
2010
Revised:
1
October
2010
Published online:
3
December
2010
The finite-field scalar relativistic coupled cluster and configuration
interaction, as well as the spin-orbit configuration interaction,
methods are employed to calculate the static dipole polarizabilities for the
lowest (6s2) 1S, (6s6p) Po and (6s5d)
D excited
states of atomic ytterbium. The results agree very well with existing
experimental and best
theoretical data and refine the set of ytterbium polarizabilities known so
far. Similar techniques are used to calculate the electric quadrupole moments
for the
Po and
D states.
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2010