Isomer-selected photoreactions of gas-phase cluster ions
Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai, 980-8578, Japan
Corresponding author: a email@example.com
Published online: 24 January 2009
We have developed an apparatus for investigating isomer-selected photodissociation reactions by ion mobility spectrometry coupled with time-of-flight mass spectrometry. By using this apparatus we optimized ion intensities under isomer-separation condition for carbon cluster ions. Among ions having linear and cyclic isomers, we demonstrated dissociation of isomer-selected C9+ ion at 355-nm photon irradiation. As a result we observed marked difference in the dissociation pathways between from linear isomer and from cyclic isomer. For the purpose of adopting this technique to metal-ligand cluster ions, we also investigated mobility spectrometry of vanadium metal ions with Ar, in addition to electronic state separation for free atomic ions.
PACS: 36.40.-c – Atomic and molecular clusters / 36.40.Qv – Stability and fragmentation of clusters
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2009