https://doi.org/10.1140/epjd/e2008-00150-y
Fine-structure energy levels, oscillator strengths and lifetimes in Co XV *,**
1
Department of Physics, S. D. (Postgraduate) College, Muzaffarnagar, 251 001, India (affiliated to Chowdhary Charan Singh University, Meerut, 250 004, India)
2
Department of Physics and Center for Theoretical Studies of Physical
Systems, Clark Atlanta University, Atlanta, Georgia 30314, USA
Corresponding author: a g_p_guptal@yahoo.co.in
Received:
8
April
2008
Revised:
25
June
2008
Published online:
1
August
2008
Excitation energies from ground state for 97 fine-structure levels as well
as oscillator strengths and radiative decay rates for all
electric-dipole-allowed and intercombination transitions among the
fine-structure levels of the terms belonging to the
(,
, and 3s3p4s configurations of Co XV are calculated, using
extensive configuration-interaction (CI) wave functions, obtained with the
CIV3 computer code of Hibbert. The important relativistic effects in
intermediate coupling are included through the Breit-Pauli approximation via
spin-orbit, spin-other-orbit, spin-spin, Darwin and mass correction terms.
Small adjustments to the diagonal elements of the Hamiltonian matrices have
been made. Our calculated excitation energies, including their ordering, are
in excellent agreement with the experimental results and the experimentally
compiled energy values of the National Institute for Standards and
Technology (NIST) wherever available. The mixing among several
fine-structure levels is found to be very strong, with most of the strongly
mixed levels belonging to the (
and
configurations. The strong mixing among several fine-structure
levels makes it very difficult to identify them uniquely. Perhaps, that may
be the reason for the lack of both experimental and theoretical results for
these levels. We believe that our extensive calculated values can guide
experimentalists in identifying the fine-structure levels in their future
work. From our radiative decay rates we have also calculated radiative
lifetimes of some fine-structure levels. In this calculation we also predict
new data for several fine-structure levels where no other theoretical and/or
experimental results are available.
PACS: 32.10.Fn – Fine and hyperfine structure / 32.70.Cs – Oscillator strengths, lifetimes, transition moments / 95.30.Ky – Atomic and molecular data, spectra, and spectral parameters
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2008