https://doi.org/10.1140/epjd/e2005-00109-6
Time-dependent spectrum of thermionic emission from hot C
Laboratoire de Spectrométrie Ionique et Moléculaire,
CNRS UMR N° 5579 et Université Lyon I, Bât. Kastler 43, boulevard du 11 novembre 1918,
69622 Villeurbanne Cedex, France
Corresponding author: a bordas@lasim.univ-lyon1.fr
Received:
6
September
2004
Published online:
13
July
2005
Experimental measurements of time-dependent photoelectron spectra observed in thermionic emission of hot C60 excited by multiphoton absorption are presented. Time resolved velocity-map imaging is used to record photoelectron spectra and to disentangle direct and delayed processes. The evolution of the kinetic energy distribution of thermal electrons as a function of the delay after multiphoton excitation is described within the general formalism of the detailed balance theory. Experimental spectra obtained in the near-UV are in excellent agreement with the assumption of thermal equilibrium.
PACS: 36.40.-c – Atomic and molecular clusters / 33.60.Cv – Ultraviolet and vacuum ultraviolet photoelectron spectra
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2005