https://doi.org/10.1140/epjd/e2003-00175-8
Phase transformations in highly excited clusters
Departamento de Física Facultad de Ciencias Exactas y
Naturales, Universidad de Buenos Aires, Pabellón 1 Ciudad Universitaria,
1428 Buenos Aires, Argentina
Corresponding author: a codorso@df.uba.ar
Received:
10
September
2002
Published online:
3
July
2003
In this communication we analyze the behavior of excited drops that undergo fragmentation. We focus our attention on two scenarios: in the first one the system is free to expand, while in the second one it is confined inside a spherical volume. It is shown that the caloric curve of free expanding systems does not display a vapor branch. In the case of constrained ones, they behave as undergoing a first order phase transition at low densities while as a second order one at high densities. The transition from liquid-like to vapor-like behavior is signaled both by the caloric curves and thermal response functions.
PACS: 64.60.Qb – Nucleation / 64.70.Fx – Liquid-vapor transitions / 31.15.Qg – Molecular dynamics and other numerical methods
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2003