Fragmentation of neutral Cn clusters (n≤9): experimental and theoretical investigations

G. Martinet; M. Chabot; K. Wohrer; S. Della Negra; D. Gardès; J. A. Scarpaci; P. Désesquelles; V. Lima; S. Díaz-Tendero; M. Alcamí; P.-A. Hervieux; M. F. Politis; J. Hanssen; F. Martín

doi:10.1140/epjd/e2003-00102-1

2018 Impact factor 1.331

Atomic, Molecular, Optical and Plasma Physics

Eur. Phys. J. D 24, 149-152 (2003)
https://doi.org/10.1140/epjd/e2003-00102-1

Fragmentation of neutral C_n clusters (n≤9): experimental and theoretical investigations

G. Martinet¹, M. Chabot¹, K. Wohrer²^a, S. Della Negra¹, D. Gardès¹, J. A. Scarpaci¹, P. Désesquelles¹, V. Lima¹, S. Díaz-Tendero³, M. Alcamí³, P.-A. Hervieux⁴, M. F. Politis², J. Hanssen⁴ and F. Martín³^b

¹ Institut de Physique Nucléaire, Université Paris-Sud, 91406 Orsay Cedex, France
² GPS, Université Paris 6 (CNRS UMR 75088) , 2 place Jussieu, 75251 Paris Cedex 05, France
³ Departamento de Química C-IX, Universidad Autónoma de Madrid, 28049 Madrid, Spain
⁴ LPMC, Institut de Physique, Technopôle 2000, 57078 Metz, France

Corresponding authors: ^a wohrer@gps.jussieu.fr - ^b fernando.martin@uam.es

Received: 10 September 2002
Published online: 3 July 2003

Abstract

We report on experimental and theoretical efforts designed to understand the fragmentation of small carbon clusters. Experimentally, a new detection system for high velocity fragments has been recently developed allowing the fragmentation of high velocity clusters to be totally recorded [1]. Results for the branching ratios of deexcitation of C₅ and C₉ formed by electron capture in high velocity C, C + He collisions are presented. Theoretically, the dissociation dynamics of C₅ has been investigated using a kinematical model based on the statistical theory of Weisskopf. In this model various structural quantities (geometries, dissociation energies, harmonic frequencies), are required for both the parent cluster and the fragments. They have been calculated within DFT and coupled-cluster formalisms for C_n up to n=9. In all cases, a strong correlation between measured branching ratios and calculated dissociation energies is observed.