https://doi.org/10.1140/epjd/e2002-00242-8
High resolution laser spectroscopy of NaAr: Improved interaction potential for the X 2Σ+ ground state
Technische Universität Berlin, Institut für Atomare Physik und Fachdidaktik,
Hardenbergstr. 36, 10623 Berlin, Germany
Corresponding author: a dz@kalium.physik.tu-berlin.de
Received:
28
August
2002
Revised:
15
October
2002
Published online:
17
December
2002
The absorption spectrum of NaAr has been investigated with high resolution using a supersonic beam of molecules and a tunable dye laser. About 3 300 absorption lines due to the transition and have been observed. In addition, we observed the spectral distribution of the fluorescence for a particular absorption line. From all experimental data the interaction potential has been deduced in a fully quantum–mechanical method of approach. The potential is given in terms of an analytical Hartree-Fock-Dispersion function. For the equilibrium parameters of the X state we get Å and .
PACS: 33.20.Kf – Visible spectra / 33.20.Vq – Vibration-rotation analysis
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2003