https://doi.org/10.1140/epjd/e2002-00223-y
Role of electric field polarisation in rotational transitions
1
Department of Physics and Astrophysics, University of Delhi, Delhi-110007, India
2
Department of Physics, Swami Shardhanand College, Alipur, University of Delhi, Delhi-110036,
India
Corresponding authors: a nsinghal@physics.du.ac.in - b vnautiyal@himalaya.du.ac.in - c manmohan@physics.du.ac.in
Received:
22
March
2002
Revised:
15
July
2002
Published online:
6
November
2002
The molecular dynamics of polar diatomic molecule, interacting with linearly and circularly polarised laser field is studied. Non-perturbative quasi-energy technique is used to determine the rotational field surfaces. Degeneracy in different M-levels is found to be removed in the presence of circularly polarised electromagnetic radiation. In this paper, we present the calculations exhibiting the dynamics of rotational excitation of a linear molecule and characteristic features of spectra which become observable in considered fields.
PACS: 33. – Molecular properties and interactions with photons
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2002