https://doi.org/10.1007/s100530170006
Inversion analysis of K2 coupled electronic states with the Fourier grid method
1
Institut für Quantenoptik, Universität Hannover, Welfengarten 1, 30167 Hannover,
Germany
2
Laboratoire Aimé Cotton (UPR 3321 du CNRS) ,
CNRS, bâtiment 505, Campus d'Orsay, 91405 Orsay Cedex, France
Corresponding authors: a dulieu@lac.u-psud.fr - b tiemann@iqo.uni-hannover.de
Received:
12
June
2001
Revised:
3
September
2001
Published online: 15 December 2001
We present a new determination of the potential curves and interactions
of the coupled electronic states and
of the potassium dimer,
based on new laser spectroscopy measurements within a molecular beam, combined with data
available in the literature. We used a new global deperturbation approach, involving
the Fourier Grid Hamiltonian method for energy level calculation. A standard deviation
of 1.2 is obtained corresponding to a variance of
cm-1,
representing a significant improvement compared to the standard deviation of 4 yielded
by the traditional local deperturbation approach.
PACS: 32.80.Pj – Optical cooling of atoms; trapping / 34.50.Rk – Laser-modified scattering and reactions
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2001