https://doi.org/10.1007/s100530170058
Growth of tellurium clusters in presence of metal impurities
Institut für Physikalische Chemie und Elektrochemie, Universität Hannover, Callinstrasse 3-3a, D-30167
Hannover, Germany
Corresponding author: a herwig@bunsen.pci.uni-hannover.de
Received:
28
November
2000
Published online: 15 September 2001
The growth of small tellurium clusters in helium and
the influence of a metal impurity (dysprosium atoms) on the cluster size
distribution are investigated in a double laser vaporization source.
A model describing the role of the carrier gas as collision partner is
presented, emphasizing the crucial influence of the gas pressure on cluster
formation.
Changes in cluster reactivity due to dysprosium
addition are discussed in terms of ionic structures
containing a radical electron.
PACS: 36.40.Jn – Reactivity of clusters / 36.40.Qv – Stability and fragmentation of clusters / 34.10.+x – General theories and models of atomic and molecular collisions and interactions (including statistical theories, transition state, stochastic and trajectory models, etc.)
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2001