https://doi.org/10.1007/s100530170266
Excited states of Ne isoelectronic ions: SAC-CI study
Department of Synthetic Chemistry and Biological Chemistry, Faculty of Engineering,
Kyoto University, Kyoto 606-8501, Japan
Corresponding author: a hiroshi@sbchem.kyoto-u.ac.jp
Received:
26
July
2000
Revised:
14
September
2000
Published online: 15 February 2001
Excited states of the s, p, and d symmetries up to principal quantum number n=4 are studied for the first eight members of Ne isoelectronic sequence (Ne to Cl7+) by the SAC-CI (symmetry-adapted-cluster configuration-interaction) method. The valence STO basis sets of Clementi et al. and the optimized excited STO are used by the STO-6G expansion method. The calculated transition energies agree well with the experimental values wherever available.
PACS: 31.50.+w – Excited states / 31.25.Jf – Electron-correlation calculations for atoms and ions: excited states / 34.60.+z – Scattering in highly excited states (e.g. Rydberg states)
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2001
