https://doi.org/10.1007/s100530170281
Spectroscopic studies on Yb+ ions in liquid helium
Department of Molecular Structure,
Institute for Molecular Science,
Myodaiji, Okazaki 444-8585, Japan
Corresponding author: a moriwaki@ims.ac.jp
Received:
27
December
1999
Revised:
31
July
2000
Published online: 15 January 2001
An emission spectrum of the 
-
(D1) transition and excitation spectra of the -
(J=1/2 (D1) and 3/2 (D2)) transitions of Yb+ ions in liquid helium have been observed by means of a laser-induced fluorescence method.
It has been found that all these spectra are blue-shifted from the ones in the free space, and also that the D2 excitation spectrum has double peaks.
To understand these spectra, theoretical calculations have also been carried out based on a vibrating bubble model, in which the bubble surface is assumed to vibrate in the spherical (breathing), dipolar and quadrupolar modes.
As a result, it has been found that the blue shifts are well understood with this bubble model, and also that the dynamic Jahn-Teller effect due to the quadrupole vibration of the bubble plays an important role for the double-peaked profile of the D2 excitation spectrum.
PACS: 32.30.Jc – Visible and ultraviolet spectra / 36.40.Mr – Spectroscopy and geometrical structure of clusters / 67.40.Yv – Impurities and other defects
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2001
