https://doi.org/10.1140/epjd/e2006-00007-5
Energy, fine structure, and hyperfine structure of the core-excited states 1s2s2pnp 5P (n = 2–5) and 1s2p2mp 5S (m = 2–5) for Li- ion
1
Department of Physics, Beijing Institute of Technology, Beijing, 100081, P.R. China
2
Department of Chemistry, Kansas State University, Manhattan, KS, 66506, USA
Corresponding author: a goubing@sina.com
Received:
4
July
2005
Revised:
24
September
2005
Published online:
10
January
2006
The relativistic energies, the oscillator strength, and the lifetimes of high-lying core-excited states 1s2s2pnp 5P (n=2–5) and 1s2p2mp 5So (m=2–5) of Li- ion are calculated with the saddle-point variational method and restricted variation method. The fine structure and the hyperfine structure of the core-excited states for this system are also explored. The results are compared with other theoretical and experimental data in the literature.
PACS: 31.30.Jv – Relativistic and quantum electrodynamic effects in atoms and molecules / 32.10.Fn – Fine and hyperfine structure / 32.70.Cs – Oscillator strengths, lifetimes, transition moments
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2005